Innovative approach to use guayule resin as a bio-based asphalt alternative

Asphalt cement will not last long as the world encounters a diminishment in crude oil. Novel resources can contribute to replacing asphalt with the sustainable, flexible pavement. This study presented guayule resin (guayule) as an innovative bio-based asphalt alternative. Ground tire rubber was used as an asphalt enhancer. To judge the guayule\u27s contribution, guayule-based binders were investigated and compared to control asphalt and asphalt-rubber binders. Binders were assessed according to comprehensive Superpave criteria and advanced rheological tests. Component analysis was performed to link the microscale level with the macroscale level. To validate the novel binder, satisfying mix performance tests were conducted. The outcomes revealed a lower viscosity for guayule than asphalt, indicating savings in plant energy consumption. Guayule had similarities with asphalt in component composition and rheological behavior with temperature susceptibility. Asphalt-guayule interaction yielded a physical blending with no chemical reaction. Rubber enhanced guayule at high temperatures, but not as much as asphalt, as proven by polymeric component migration through liquid binder due to depolymerization occurred. However, because of strong oxidation bonding chains attributed to guayule, the oxidative aging negatively affected the guayule-based binder’s long-term distresses. Validation by mix performance assessment revealed that guayule supported mix stability against moisture (particularly at lower air contents), rutting, and fatigue cracking, but had low thermal fracture resistance. In a nutshell, guayule had potential to replace conventional asphalt to compensate or surpass the asphalt performance required partially or even entirely at specific grades --Abstract, page iii

Game-Theoretic Frameworks and Strategies for Defense Against Network Jamming and Collocation Attacks

Modern networks are becoming increasingly more complex, heterogeneous, and densely connected. While more diverse services are enabled to an ever-increasing number of users through ubiquitous networking and pervasive computing, several important challenges have emerged. For example, densely connected networks are prone to higher levels of interference, which makes them more vulnerable to jamming attacks. Also, the utilization of software-based protocols to perform routing, load balancing and power management functions in Software-Defined Networks gives rise to more vulnerabilities that could be exploited by malicious users and adversaries. Moreover, the increased reliance on cloud computing services due to a growing demand for communication and computation resources poses formidable security challenges due to the shared nature and virtualization of cloud computing. In this thesis, we study two types of attacks: jamming attacks on wireless networks and side-channel attacks on cloud computing servers. The former attacks disrupt the natural network operation by exploiting the static topology and dynamic channel assignment in wireless networks, while the latter attacks seek to gain access to unauthorized data by co-residing with target virtual machines (VMs) on the same physical node in a cloud server. In both attacks, the adversary faces a static attack surface and achieves her illegitimate goal by exploiting a stationary aspect of the network functionality. Hence, this dissertation proposes and develops counter approaches to both attacks using moving target defense strategies. We study the strategic interactions between the adversary and the network administrator within a game-theoretic framework. First, in the context of jamming attacks, we present and analyze a game-theoretic formulation between the adversary and the network defender. In this problem, the attack surface is the network connectivity (the static topology) as the adversary jams a subset of nodes to increase the level of interference in the network. On the other side, the defender makes judicious adjustments of the transmission footprint of the various nodes, thereby continuously adapting the underlying network topology to reduce the impact of the attack. The defender\u27s strategy is based on playing Nash equilibrium strategies securing a worst-case network utility. Moreover, scalable decomposition-based approaches are developed yielding a scalable defense strategy whose performance closely approaches that of the non-decomposed game for large-scale and dense networks. We study a class of games considering discrete as well as continuous power levels. In the second problem, we consider multi-tenant clouds, where a number of VMs are typically collocated on the same physical machine to optimize performance and power consumption and maximize profit. This increases the risk of a malicious virtual machine performing side-channel attacks and leaking sensitive information from neighboring VMs. The attack surface, in this case, is the static residency of VMs on a set of physical nodes, hence we develop a timed migration defense approach. Specifically, we analyze a timing game in which the cloud provider decides when to migrate a VM to a different physical machine to mitigate the risk of being compromised by a collocated malicious VM. The adversary decides the rate at which she launches new VMs to collocate with the victim VMs. Our formulation captures a data leakage model in which the cost incurred by the cloud provider depends on the duration of collocation with malicious VMs. It also captures costs incurred by the adversary in launching new VMs and by the defender in migrating VMs. We establish sufficient conditions for the existence of Nash equilibria for general cost functions, as well as for specific instantiations, and characterize the best response for both players. Furthermore, we extend our model to characterize its impact on the attacker\u27s payoff when the cloud utilizes intrusion detection systems that detect side-channel attacks. Our theoretical findings are corroborated with extensive numerical results in various settings as well as a proof-of-concept implementation in a realistic cloud setting

A Threshold to Utilize Guayule Resin as a New Binder in Flexible Pavement Industry

This study denotes a threshold to utilize Guayule Resin as a new bio-based binder or asphalt cement (AC) proportion, both with/out crumb rubber modifier (CRM), regarding solutions for environment, cost, and sustainability aspects. Via this research, 15 designated binders will be presented, all of them were tested as unaged and RTFO, whereas eight binders proceeded with PAV. Superpave was utilized to study their physical properties. Viscosity was examined upon some guayule-based binders with/out CRM, getting 114cP (at 135℃) for BGR, increased to about 3 times with 10%CRM (by weight of liquid binder) and about 7-8 times with 20%CRM. Comparisons among binders will be depicted regarding six categories (Neat AC, Neat BGR, AC+BGR, BGR+CRM, AC+CRM, and AC+BGR+CRM). This study initiates a perspective to judge designated binders and get benefit upon performance required. That\u27s why the study reported outcomes regarding the effectiveness of the binder\u27s stiffness, elasticity and performance. Results showed 20%CRM raised BGR performance by about one grade, compared to 5%CRM for AC to boost the same one grade. On another side, RTFOT showed a high mass loss for guayule-based binders, reaching 8.5% for unconditioned BGR, but about 5% by a heat-treatment process. The low-temperature grade was presented for all guayule-based binders indicating a-10 grade

Performance Assessment of Bioasphalt Mixtures Containing Guayule Resin as an Innovative Biobased Asphalt Alternative

Guayule resin was investigated through mixture to assess its role in the field performance. For performance comparisons, conventional asphalt, neat guayule, asphalt-rubber-guayule, and guayule-rubber binders were implied. Field-simulated lab mixtures were made to investigate the major distresses. Modified Lottman, rut, semicircular bending, and disk-shaped compact tension tests were used to assess stripping, rutting, fatigue, and thermal cracking resistances. Stripping and rutting susceptibilities were also assessed by Hamburg wheel-tracking test. The outcomes disclosed that when the modified Lottman test was used, guayule containing a 7% air content was more susceptible to stripping than that containing a 3.5% air content, resulting in tensile strength ratios of 40% and 71%, respectively. All investigated mixtures did not reach out the stripping inflection point under the Hamburg wheel-tracking criteria. Asphalt offered the worst Hamburg rut depth, which was 3.2 mm after 20,000 passes. Guayule-based mixtures perfectly resisted rutting as proven by the rut test. Guayule offered the worst rut depth of 6.3 mm, indicating a great rutting resistance. The guayule-based mixture had a high fracture toughness at intermediate temperatures. Guayule and guayule-rubber mixtures offered a critical strain energy release rate of 0.65-0.69 kJ/m2 compared to 0.46 kJ/m2 for asphalt. They, however, tended to possess low thermal fracture resistance (less than the threshold fracture energy, 400 J/m2). Conversely, a blend of 62.5% asphalt, 12.5% rubber, and 25% guayule offered 591 J/m2 at its performance grade low temperature (-16°C) and 409 J/m2 at -22°C compared to 429 J/m2 for asphalt at the later temperature, which represented the performance-grade low temperature of asphalt

Evaluation of Guayule Resin as an Innovative Bio-Based Asphalt Alternative in MIX Performance -- Preprint

Literature revealed the potential of using guayule resin for asphalt cement replacement from the binder’s perspective. However, monitoring guayule resin through binder-aggregate mixture could disclose its performance through field. In this study, designated binders were employed to investigate the applicability of such an innovative replacer through mixture, which were neat asphalt and guayule-based binders (neat guayule, asphalt-rubber-guayule, guayule-rubber binders). Consecutively, field-simulated lab mixtures were prepared to investigate the major distresses. Moisture damage, rutting, fatigue cracking, and thermal cracking resistances were investigated using the modified Lottman (TSR) test, rut test by asphalt pavement analyzer (APA), semi-circular bending (SCB) test, and disk-shaped compact tension (DCT) test, respectively. Additionally, the Hamburg wheel-tracking (HWT) test was employed to evaluate moisture susceptibility and rutting resistance. Outcomes revealed that the neat guayule was susceptible to moisture damage at a 7% air content (Va) when the TSR test was employed. In contrast, all investigated mixtures yielded perfect performances against moisture susceptibility under the HWT test. Guayule-based mixtures perfectly resisted rutting, as analyzed by the rut test and HWT test. Generally, changing parameters (e.g., Va, rubber addition, and partial asphalt replacement by guayule and rubber) enhanced the guayule-based mixture resistance to rutting and moisture damage resulting in acceptable performances. Guayule-based mixture had a high fracture toughness at low temperatures, hence fatigue fracture resistance at intermediate temperatures. Neat guayule mixture with or without rubber addition did not entirely resist thermal fracture. However, partial asphalt replacement by guayule and rubber resisted the thermal fracture to a great extent

Influence of Guayule Resin as a Bio-Based Additive on Asphalt-Rubber Binder at Elevated Temperatures

This study seeks to find the influence of replacing a portion of the asphalt–rubber binder with the bio-based material “guayule resin.” This replacement could be beneficial in terms of sustainability, economics, and environmental concerns related to the asphalt industry. Nine asphalt-rubber-guayule binders were investigated to find their rheological properties. Consecutively, the study proceeded with five selected binders being compared to the original asphalt (PG64-22). Investigations underwent whole matrices (crumb rubber modifier (CRM) residue included) and liquid phases (CRM residue extracted). Additionally, these properties were partially sought for their corresponding asphalt–rubber binders to compare and judge the contribution of the guayule resin. Likewise, a thermo-gravimetric analysis was done for the guayule resin to recognize its moisture and composition complexity. Such an analysis was also done for the as-received CRM and some extracted CRMs to determine the release and residue of rubber components. Outcomes showed that the guayule resin has the potential to compensate the performance required against the original asphalt at elevated temperatures while greatly decreasing the asphalt cement proportion. For instance, a blend of 62.5% asphalt, 12.5% CRM, and 25% guayule resin provided better performance than that of the original asphalt

Component Analysis of Bio-Asphalt Binder Using Crumb Rubber Modifier and Guayule Resin as an Innovative Asphalt Replacer

This research seeks to interpret the component analysis of an innovative bio-asphalt binder using guayule resin in addition to crumb rubber modifier (CRM) at high concentrations. Such asphalt modification aims to minimize the dependency on virgin asphalt binder and provide new solutions concerning sustainable, flexible pavement industry. Guayule resin is a promising bioresource for asphalt binder replacement. By now, it could be considered a no value byproduct extracted during the guayule natural rubber production. CRM is a recycled material derived from scrap tires. The provided interpretation could help in understanding the asphalt-rubber-guayule interaction mechanism. Fourier transform infrared spectroscopy (FTIR), supported by thermo-gravimetric analysis (TGA), was used to investigate the component analyses of guayule resin composition, asphalt guayule interaction, and asphalt rubber guayule interaction, compared to corresponding asphalt rubber interaction. Additionally, the rheological properties at elevated temperatures were provided to link the microscale properties with the final product performance. The study clarified the distinct carbon and hydrogen compositional elements of guayule resin. Asphalt and guayule resin have similarities in chemical composition and rheological behavior with temperature susceptibility. The asphalt guayule binder had physical interaction. However, when both interacted with rubber, a chemical interaction was attributed, with no difference in rubber dissolution tendency, in asphalt rubber guayule, compared to asphalt rubber. A bio-binder composed of 62.5% asphalt, 25% guayule and 12.5% CRM had the potential to provide rheological properties better than base asphalt. Such behavior was interpreted by a high release of rubber components

Quantitative Evaluation of Asphalt Binder Extraction from Hot Mix Asphalt Pavement using Ashing and Centrifuge Methods

Asphalt binder requires more investigation to be accurately and precisely extracted since it is an effective procedure for quality assurance quality control (QA/QC) and subsequent binder characterization. In this research, the authors presented a hands-on experience with binder extraction to deliver recommendations concerning the sensitive steps that may affect the outcomes (extracted binder content, Pbe%). Two mineral matter determination methods (ashing and centrifuge) were addressed based on the centrifuge extraction method. Field cores were investigated by comparing the Pbe% to the actual binder content, Pba%. Analysis of variance (ANOVA) and Tukey Post-Hoc statistical analyses, in addition to linear least square regression analysis, were used to show the significance of difference according to 38 variant cores randomly obtained from the field segments (in-service roads) via the first two weeks from their construction dates. Such cores involved reclaimed asphalt pavement (RAP), reclaimed asphalt shingles (RAS), and a wide range of additives. The two extraction methods were compared, concluding that the centrifuge method was highly recommended based on a quantitative evaluation, which delivered the same average Pba% based on the 38 cores. Furthermore, the centrifuge method provided much saving in the experimental time (almost half the time required for the ashing method). It was found that the ashing outcomes were equal to the centrifuge outcomes when disregarding the ammonium carbonate addition. Thus, it could be recommended to reassess the ammonium carbonate addition as it might excessively compensate for minerals that have not been lost by the ignition oven

Quantitative Evaluation of Asphalt Binder Extraction from Hot Mix Asphalt Pavement Using Ashing and Centrifuge Methods

Asphalt binder requires more investigation to be accurately and precisely extracted since it is a significant procedure for quality control quality assurance (QC/QA) and subsequent binder characterization. In this research, the authors provided a hands-on experience with binder extraction to deliver recommendations concerning the sensitive steps that may affect the outcomes (extracted binder content, Pbe %). Based on the extraction by the centrifuge method, two mineral matter determination methods (ashing and centrifuge) were addressed. Field cores were investigated with comparing the Pbe % to the actual binder content, Pba %. Analysis of variance (ANOVA) and Tukey Post-Hoc statistical analyses, in addition to linear least square regression analysis, were used to show the significance of difference according to 38 variant cores randomly obtained from the field segments (in-service roads) via the first two weeks from the construction date. Such cores involved reclaimed asphalt pavement (RAP), reclaimed asphalt shingles (RAS), and a wide range of additives. The two extraction methods were compared with concluding that the centrifuge method was highly recommended based on a quantitative evaluation, which delivered the same average Pba % based on the 38 cores. Furthermore, the centrifuge method provided much saving in the experimental time (almost half the time required for the ashing method). It was found that the ashing outcomes were equal to the centrifuge outcomes with disregarding the ammonium carbonate addition. Thus, it could be recommended to reassess the ammonium carbonate addition as it might excessively compensate for fake minerals that have not been lost by the ignition oven